Sn2 reaction Study guides, Class notes & Summaries

Test Bank for Organic Chemistry 4e 4th Edition by David R. Klein. ISBN-13: 9594 Full chapters test bank PDF TABLE OF CONTENTS 1 A Review of General Chemistry: Electrons, Bonds, and Molecular Properties 1 1.1 Introduction to Organic Chemistry 2 1.2 The Structural Theory of Matter 3 1.3 Electrons, Bonds, and Lewis Structures 4 1.4 Identifying Formal Charges 7 1.5 Induction and Polar Covalent Bonds 8 1.6 Reading Bond-Line Structures 11 1.7 Atomic Orbitals 14 1.8 Vale...

SN1 Reaction - ANSWER- Unimolecular nucleophilic substitution - 2 steps - Starting with enantiomerically pure product tends to result in some degree of racemization - Retention AND inversion at stereocenter (R and S) - 1 nucleophile is replaced by another nucleophile - Carbocation INTERMEDIATE forms - Rate is dependent only on substrate concentration 1. LG leaves, forming a carbocation 2. Nucleophile attacks the carbocation, forming the product SN2 Reaction - ANSWER- Bimolecular nuc...

General Chemistry ACS EXAM (2015 version) 60 Questions with Verified Answers A 20.0 g sample of mercury(II) oxide (HgO, M = 216.6) is heated strongly, causing it to decompose to metallic Hg and O2 gas. What volume of O2 gas is produced (measured at STP)? (A) 1.03 L (B) 2.07 L (C) 4.14 L (D) 14.0 L - CORRECT ANSWER A When 30.0 mL of 0.10 M AgNO3 is added to 30.0 mL of 0.10 M NaCl, aqueous NaNO3 and solid AgCl are formed. How much solid AgCl is produced? (A) 0.0030 mol (B) 0.0...

DAT Organic Chemistry Review Practice Test. Which are more stable conformers - CORRECT ANSWER staggered What are the rate laws of SN2 and E2 reactions - CORRECT ANSWER rate= k [RX][Nu:-] rate depends on concentrations of alkyl halide and nucleophile What are the rate laws of SN1 and E1 reactions - CORRECT ANSWER rate= k[RX] rate only depends on the concentration of the alkyl halide E2 elimination reactions must occur in bonds that are - CORRECT ANSWER coplanar or antiperiplan...

Chem 210 – Reactions Questions 100% Answered!! Reagent = Nucleophile Only - ANSWER1° = Sn2 2° = Sn2 3° = Sn1 + E1 (polar medium necessary) Reagent = Strong Nucleophile & Strong Base - ANSWER1° = Sn2 2° = E2 3° = E2 Reagent = Weak Nucleophile and Weak Base - ANSWER1°/2° = No Reaction 3°/resonance stabilized carbocation = Sn1 + E1 (polar medium necessry Reagent = Base Only - ANSWER1° = E2 or Sn2 (if unhindered and no beta-hydrogen with unhindered base) 2° = E2 3° = E...

what factors explain the outcomes of reactions? hybridization, delocalization, eN, atom density what is a leaving group? - group of atom(s) that can be stable on its own - eN atoms that are good LG also make strong acids what is the α carbon? C directly attached to leaving group what are β Cs? β Hs? βC: C(s) attached to α carbon βH: H(s) attached to βC what is a LB? is it a nucleophile or electrophile? lewis base, nucleophile what is nucleophilic ...

Reagent = Nucleophile Only - ANSWER1° = Sn2 2° = Sn2 3° = Sn1 + E1 (polar medium necessary) Reagent = Strong Nucleophile & Strong Base - ANSWER1° = Sn2 2° = E2 3° = E2 Reagent = Weak Nucleophile and Weak Base - ANSWER1°/2° = No Reaction 3°/resonance stabilized carbocation = Sn1 + E1 (polar medium necessry Reagent = Base Only - ANSWER1° = E2 or Sn2 (if unhindered and no beta-hydrogen with unhindered base) 2° = E2 3° = E2 Examples of Only Nucleophiles - ANSWERCl⁻, ...

UMICH CHEM 210 - Exam #3 - Reaction Mechanisms 100% Correct SN1 Reaction - ANSWER- Unimolecular nucleophilic substitution - 2 steps - Starting with enantiomerically pure product tends to result in some degree of racemization - Retention AND inversion at stereocenter (R and S) - 1 nucleophile is replaced by another nucleophile - Carbocation INTERMEDIATE forms - Rate is dependent only on substrate concentration 1. LG leaves, forming a carbocation 2. Nucleophile attacks the carbocati...

SN2 vs SN1 vs E2 vs E1 Reaction Examples Primary Substrate with Strong Nuc / Strong Base: Primary Substrate with Strong Nuc / Weak Base: Primary Substrate with Weak Nuc / Strong Base: Primary Substrate with Weak Nuc / Weak Base:

Orgo Synthesis Questions & Answers A+ Review Alcohol Synthesis from Methyl - ANS-NaOH (SB) --> Sn2 Substitution of OH and LG Alcohol Synthesis from 1*C - ANS-NaOH (SB) --> Sn2 Substitution of OH and LG Alcohol Synthesis from 2*C - ANS-Na(OAc) + NaOH --> SnAc Substitution of OH and LG Alcohol Synthesis from 3*C - ANS-H20 (WB) --> Sn1 Substitution of OH and LG (C+ Rearrangement) Alcohol Elimination (Dehydration) from Methyl - ANS-No reaction Alcohol Elimination (Dehydration)...