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Organic Chemistry ACS Final Exam Study Guide

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Organic Chemistry ACS Final Exam Study Guide Basicity rules - Answer--strong base: unstable/reactive (ED groups) -weak base: stable (EW groups/more EN/bigger) Chair conformation - Answer--more stable equitorial (slanted) -pointing up/pointing down=cis if both up -elimination: trans and diaxia...

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  • October 6, 2024
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EmillyCharlotte
EMILLYCHARLOTTE 2024/2025 ACADEMIC YAER ©2024 EMILLYCHARLOTTE. ALL RIGHTS RESERVED
FIRST PUBLISH SEPTEMBER 2024




Organic Chemistry ACS Final Exam
Study Guide

Basicity rules - Answer✔✔--strong base: unstable/reactive (ED groups)


-weak base: stable (EW groups/more EN/bigger)


Chair conformation - Answer✔✔--more stable equitorial (slanted)


-pointing up/pointing down=cis if both up


-elimination: trans and diaxial


Newman projection - Answer✔✔--gauche: substituent groups adjacent to eachother


-grab middle and turn to put in plane


Enantiomers - Answer✔✔--not superimposable mirror images


-same besides stereochemistry


Diastereomers - Answer✔✔--mirror images but one stereocenter stays and another is changed


Meso - Answer✔✔--at least two stereo centers


Alkene + HBr - Answer✔✔--adds Markonikov


Fischer projection - Answer✔✔--vertical plane: away


-horizontal plant: towards



Page 1/8

, EMILLYCHARLOTTE 2024/2025 ACADEMIC YAER ©2024 EMILLYCHARLOTTE. ALL RIGHTS RESERVED
FIRST PUBLISH SEPTEMBER 2024


-assign priorities


-turn 90 then put on side


Electrophilic addition to alkene - Answer✔✔--forms carbocation


-E+ adds


1.Hg(OAc)2, H2o


2.NaBH4


alkene - Answer✔✔--forms mercurnium ion


-no rearrangement


-Mark addition of OH


1. B2H2


2.H2O2, NaOH


alkene - Answer✔✔--anti-Mark addition of OH


-syn addition of the H added


Br2 to alkene - Answer✔✔--anti addition


-adds to both sides


-could be allylic shift; 1,2 and 1,4 mixture


1.H2o,H2SO4


2. HgSO4

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