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electrochemical exam questions bank

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Li(s) | Li+(aq) || Li+(aq) | MnO2(s) , LiMnO2(s) | Pt(s) Li+(aq) + e- → Li(s) -3.04 write a half-equation for the reaction that occurs at the positive electrode of this cell. Calculate the standard electrode potential of this positive electrode emf= 2.91 - answer-Li+ + Mn02 + e- --&gt...

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  • September 16, 2024
  • 14
  • 2024/2025
  • Exam (elaborations)
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  • Electrochemical
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TOPDOCTOR
ELECTROCHEMICAL EXAM QUESTIONS
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Li(s) | Li+(aq) || Li+(aq) | MnO2(s) , LiMnO2(s) | Pt(s)

Li+(aq) + e- → Li(s) -3.04

write a half-equation for the reaction that occurs at the positive electrode of
this cell.

Calculate the standard electrode potential of this positive electrode
emf= 2.91 - answer-Li+ + Mn02 + e- --> LiMn02(s)




2.91 = (x) - (-3.04)

even though oxidation, don't change sign

explain the function of salt bridge? - answer-ions in ionic substance in salt
bridge
move through salt bridge
to maintain charge + balance

use data to
justify why S042- ions
should not be capable of oxidising Br- ions? - answer-E* for S042- <

what are the 2 ways to use hydrogen as fuel for cars.




what is the major advantage of using fuel cell? - answer-one way in fuel cell
to power an electric motor
or as fuel in an internal combustion engine



internal combustion engine wastes > energy

, aluminium used as electrode is rubbed with sand paper before use, explain
why? - answer-To remove oxide layer on aluminium

what would you draw for diagram of a right hand standard hydrogen
electrode with no salt bridge? - answer-H2 gas
given below the electrode
Pt electrode

how can a simple salt bridge be prepared?




In aluminium and hydrogen fuel cell why would this be unsuitable? - answer-
dipping filter paper
into KC032


C032- ions react with acid (H+)
in standard hydrogen electrode
or with Al3+

conc of H+ / Al3+ change / EMF

identify the weakest reducing agent from species in table?
explain how you deduced your answer? - answer-(least oxidising --> so look
on RHS)
(reducing = LFH)

Species on RHS has largest electrode potential + E*

can normal cell reactions be recharged and why? - answer-no

cell reactions not reversed
(Zn oxidised to Zn0)

Zn0 not be reduced to Zn
by passing current through

explain how salt bridge D
provides an
electrical connection between the 2 electrodes?

suggest why KCl not suitable salt for salt bridge in this cell? - answer-ions
able to move through

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