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Reaction Mechanism Explained in detailed (ALL) $8.19   Add to cart

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Reaction Mechanism Explained in detailed (ALL)

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Handwritten Digital Reaction Mechanism Organic Chemistry Notes with colourful text for easy and in depth understanding of the topic specially for NEET and JEE entranced focused students

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  • May 27, 2023
  • 4
  • 2022/2023
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Retention Inversion



RETONANISMS Nucleophilicity order:
CD
intermediate product product.




(i)
-




R
R R
I
is

Nu-C

Es
c -Nu +
*
Six cr> Icon Es
yarents,
> 3> Br H


ph-o> R-OR> 420. ↳
-




>


↳g*w]
F Racemic mixture.
CH3l0o-<c- >
Me can attack from any
Polar side thus Race mic

Non-polar mixture
is formed.
- ⑦


W



Benzene
polar polar Strong me but weak basic charac
·



T.S I T.S #
·




cyclohexane Aprotic protic Si, I, B, C, F,cr, N, R-5- -




(Ether) Rate
of six
stability of c
&



2C14
·

Cry-O-CH3 ·
U- 04


·
Cry-Y-Cry (Retore)
·
R-OH
⑰ X




l Tyxyxf
Strong with base. -
R-COOH new
strong
·




·

CHI-Y-Cy (Dimethyl
sulfoxide amso). RNUz
CHI, on
IIIE
RT, R-0,
-CH3 (Dimethyl
·

n-Y-N-CH3 formamide
DME) NO SNI

(Dimethyl
Cr3 --N-c- ⑭weak
amenit
->
Acetamide DMA) mewith to wear
·

base
CH3
strong -
7 icy determining
SN
-


Rate
the
of
R-O4 > H20
nucleophilicity.
Electrophiles: (leveis acids) -

SN'IN R -X ·






44, R4, 44, Be, I, NOY,
upSo
R
#AgNOs catalystof
↳NG
is a x
NOz
-




eg. AgNO3
LEAVING GRO e in ag. medium.
SO3, carbene +

Yt Agxd
1 -

R +




productR-OH
pt2 ,
AgY, Ag2t Exmp.

*Un, wa,*
H20
-




·
On <
#




positively charged but
n ot Inst. ·
N42 < NH3 super leaving: CF3so;<cntgso; Solvolysis reach:-SN in which solentm i


groups:
-




Neutral
-




Allz, BF, BC3, zndz · sn*<H2s neo-hydrolysis In case
of 420, little ant




-- Tosylate
must be
-- of alcohol/Acctone
·
NH3 <PH3 as -ay ion -
(G.L) cry or
->Acctolysis taken to dissolve R-X




Nucleophiles:Hemis Bases) Alcolysis
->
R-on



100,ox, it -as-on
R
an3
·




They
donate epair to
an
e-deficientcenter accept t 1500, He
e al3 -
-
⑰ in
0
M




I
-
Noz
CH3 CH3
Mucleophiles not
only
do not spain to
e-deficient center CH3
·




Tosylate.
sylate Brosylate
M-K-Bu
NO
with
the
but form
an3
bond center.
they
also


in s
a**-
forms bond with n+
#,
it
--
-Base as or
4O
-




leaving groups
40 + H-x ->
HON + some can be converted
poor
8 8-+

to
good leaving CH3
no+cyc-> homs + 40 groups.
↳ nucleophile as it forms bond
I

R-on (R-8nz] - (RY +
neo.
as cry
CH3

-c-o-d-cz
O

->
crg-o--ans
poor
lg. (Mus
*/ ing is
ins
In
organic chemistry
my are
seeking species. Ts 2.
=




↳ Nucleophilicity: -speed of Attacking. Whereas
bascicity
is
·




R-o R-Ots'sgoin
ph
120/Acetone.
Ph



e
thermodynamic stability.
not
the
Kinetically governed. R-NM + Net +4 on Racemic mixture
R-N2 este
-
p
·





..Er?Neee
Electron Me
density
SACTON
I strearng
H

Electronegativity to period from key points: the
leaving group leaves e
-




only applicable in -
- ->
420/ mixture
leftto right is the R.D.S. me
Acetone.


·
Enz> re> on> ② Intermediate is carbocation.



In
organic ③ 2nd ne
the

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