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IBDP HL Chem, Redox

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In depth and simple to understand class notes taken over the course of 2 years in a highly accredited IB school for Chemistry HL, in regards to the topic of redox This includes diagrams, annotations, extensive notes and explanations and they are the notes that have solely led me to an IB 7 in HL ...

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  • February 20, 2023
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Oxidation Number

- This is a human made number, a number assigned to an element or compound or ions
- Charge is only for an ionic compound

- 10 rules for assigning oxidation numbers
Rule Example

Element by itself: 0 Xe = 0 O2 = 0 Cl2 = 0

Group 1: always +1 Na+ = +1

Group 2: always +2 Mg2+ = +2 Ca2+ = +2

Halogens: Usually -1, positive with oxygen F- = -1 Cl- = -1 ClO- = Cl is +1

Fluorine: always -1 F- = -1

Hydrogen: +1 with non-metals, -1 with metals CH4 = H is +1 NaH = H is -1

O: Usually -2, -1 in peroxide (H2O2) H2O = O is -2 H2O2 = O is -1

Monatomic ion: ion charge Na+ = +1 Mg2+ = +2 Cr3+ = +3

Sum of oxidation number for a Polyatomic ion: ion charge MnO4- = -1 Cr2O72- = -2

Sum of oxidation number for a neutral compound: 0 CH4 = 0 KMnO4 = 0

- For writing
- Charge = 3+
- Oxidation state = +3
- Oxidation number = 3

, Reduction and oxidation

1st definition (Traditional definition)
- Gain in oxygen or loss in hydrogen is oxidation
- Reduction is loss of oxygen or gain of hydrogen

2nd definition
- Oxidation is loss of the electrons (atom gets more positive)
- Reduction is gaining electrons (atom gets more negative)

3rd definition
- Increase in oxidation number is oxidation
- Decrease in oxidation number is reduction


Oxidation and reduction agents

- Oxidation agent causes oxidation, reduction agent causes reduction
- The compound undergoing oxidation is the reducing agent
- The compound undergoing reduction is the oxidation agent

• Identify the oxidising and reducing agents in the following equation.
2Al + 3PbCl2 → 2AlCl3 + 3Pb




Look at reduction and oxidation sheet

Disproportionation reaction:
Reaction where the same type of atom is oxidised and reduced
Eg. CO2 + C → 2CO
Carbon both reduced and increased


Usually, double displacement reaction is not redox, no changes in oxidation state

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