Hydroboration oxidation - Study guides, Class notes & Summaries

preparation of aldehydes and ketones from common reagents via oxidation or reduction

--NO2 + Sn/HCl - Correct Answers>Clemmenson Reduction --NH2 1,2-addition conj double bonds + RMgX or LiAlH4 - Correct Answers>Nucleophiles attack the carbonyl directly. Strong nucleophiles: Gringards, NaBH4, LiAlH4 1. (2) esters CH3--C=O--OEt + NaOR, EtOH 2. H3O+ ketone + (ester) CH3--C=O--OEt + -OR + H3O+ --> - Correct Answers>Claisen Condensation enolate ion of one ester acts as nucleophile attacking another ester 1. NaOR, EtOH 2. H3O+ Anhydride for mixed 1. BH3/TH...

This document contains digitally taken, handwritten notes for the reactions of aldehydes and ketones. It covers information including nomenclature, synthesis and reactions with strong and weak nucleophiles. It also shows how to make hemi-acetals and acetals. Other reactions include the Wittig reaction and how to synthesize and Ylide. Notes are color coded.

This document is a summary of the aldehydes and ketones chapter of the organic chemistry 2 course. It is digitally taken, handwritten notes. It covers information including nomenclature, synthesis and reactions with strong and weak nucleophiles. It also shows how to make hemi-acetals and acetals. Other reactions include the Wittig reaction and how to synthesize and Ylide. Notes are color coded and shortened for easy understanding and reviewing.

nt and each reaction box, place the best reagent and Conditions from the list below. PhLi CH3ONa in CH3OH B2H6 in THF PCC in CH2Cl2 PhCO3H in CH2Cl2 in Et20 H2O2/NaOH HaPO4, A. NaBH4 in EtOH O3 in CH2Cl2 Solution 1) B2H6 in THF 2) H2O2/NaOH 3) PCC in CH2Cl2 explanation: 1) and 2) are hydroboration-oxidation reaction that gives alcohol following anti-Markovnikov rule (OH is added to the less substituted carbon of C=C double bond) 3) oxidation of OH to ketone.

Includes reactions for alkenes, alkynes and alcohols, SN1/SN2/E1/E2 reactions, table of strong/weak nucleophiles and strong/weak bases, conditions for each type of substitution/elimination reaction to occur, how to form hoffman/zeitseff product, Radical reactions, R/S configurations and chair conformations.

Organic chemistry notes over oxidation and reduction methods for alkenes including ozonolysis. Includes practice problems.

I got a 1st in my first year studying chemistry at the University of Birmingham using these revision notes that I have uploaded. They include detail on the structure and bonding of alkenes, consequences of the pi bond, E- and Z- isomers, stability of alkenes, bonding and geometry of alkynes, acidity of alkanes, alkenes and alkynes, elimination (making alkenes from alkyl halides), the Wittig Reaction, synthesis of alkenes from alkynes, dissolving metal reduction, synthesis of alkynes from differe...