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Organic Chemistry I - Free Radical Halogenation Overview (CHEM 301)
This note covers essential, highly tested concepts for Free Radical Halogenation (FRH) (i.e. FR Bromination and Chlorination). Topics include: 
 
1. The three mechanistic steps of FRH (Initiation, Propagation, Termination) 
2. Single vs. double-headed arrows (i.e. electron-pushing diagrams) 
3. Selectivity differences between FR Bromination and FR Chlorination 
4. What is hv and NBS? 
5. Radical resonance (aka “rearrangement”)
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- • 3 pages •
This note covers essential, highly tested concepts for Free Radical Halogenation (FRH) (i.e. FR Bromination and Chlorination). Topics include: 
 
1. The three mechanistic steps of FRH (Initiation, Propagation, Termination) 
2. Single vs. double-headed arrows (i.e. electron-pushing diagrams) 
3. Selectivity differences between FR Bromination and FR Chlorination 
4. What is hv and NBS? 
5. Radical resonance (aka “rearrangement”)