Summary
Summary Notes on chapter 6 for mechanisms
- Course
- Organic Chemistry 1
- Institution
- Rutgers University
notes on chapter 6 of organic chemistry I
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HAPTERGREACTIONSOFALKENESYOSTCHARACTERISTICREACTIONOFALKENES 30 20tomethylH Ci't
thecarboncarbondoublebondtheseincludeoxidationsandreductions
ADDITIONto moststable
POLYMERIZATION WHYDOALKYLGROUPSSTABILIZECt
CH CHinitiatortethchat Inductiveeffect
NERGYDIAGRAMFORATWOSTEPREACTIONinvolvingformation of
sp ismoreelectronegativethanCsp
NINTERMEDIATE 133 251
HEATOFREACTIONdifferenceinenthalpybetweenreactantsand
p roducts selectrons
to
onaverageiscloser nucleus
REACTIONCOORDINATEmeasureinthe of
inpositions atomsduringareaction's
change
progression
TRANSITIONSTATESpeaksonthe DONOT
surfaceChemicalstructures
energy
mmmmm Filled o bond
REACTIVEINTERMEDIATEatan twotransitionstates
between
minimum
f pH
IF
energy
RATE DETERMININGSTEPstepthatcrossesthehighestenergybarrierSlowest 3 I É bt
µ q
it
Faint.IE EIIi I gystzate2
REACTIONCOORDINATEDIAGRAM
H Br F
TH TH
n transit
LECTROPHILES
D
IF f
reactioncoordinate
s
ADDITIONSTOALKENES REACTIONOFALKENES
la 1 Reaction
Jc CI actingasanucleophile reactingLewisBase
LewisacidisanELECTROPHILE
7 É
MarkoviniborCarbocation
tx y addition
Y mechanism
Ie g I e f o H
8 si on
IDDITIONOFHCI
gq
Hi HE
reaction
This is regioselectivity
Markovinikerregioselectivity
themost
carbonwith
HsgetstheH
Hq
H
IF
acarbocation
MECHANISM I ÉÉ
Hye
other
II gH
4,84 Xp
shift
hydride H
way
I
Haly
yqj.ge me Iti minor
month aft
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