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Summary - org chem 101
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organic chemistry notes about (amines and related nitrogen compounds)
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Noles allaminesare derivatives of ammonia2 primaryamine 1 thenitrogenatominaminecarries an unsharedpairofelectron
I
NH R NH R Secondaryamine caschaNit 2 thenitrogenatominamine istrivalent
R R tertiaryamine chachaN CH 3 thenitrogenorbitals are sp3hybridized
Y
m d
cuzntl methenamine ctbatlantis ethanamine 5 methylamine3ethylamine are gases
CHzchachants I propanamine 2 pentanamine 6 primaryaminewith 3 carbonormore areliquid
meth ethanamine but tertiary amine cannotformhydrogenbond
u
t r
anantamine many shortchain 8 primaryaminesecondaryamine tertiaryamineformHbond
water with
ghz otis
n ethynmothy propanamine chacha cha n oh shortchain 9 amineswithuptofive orsixcarbonsatomsare completelysolubleintho
longchain
g preparation of amine
w methylzpentanamine ohs cha cha cha cti a alkylhalide ammonia Nao primaryamine Hot wax
utica
casein schnitzel
Nao
chartistthotNac
common name for amine alkyl amine b primaryamine alkylhalide Nat Secondaryamine
chgntiz methylamine ctb cha cha ethylamine cttzntlatotizctizasctiz yyy.ci nao's cts na thotnad
dincti
cuzcha na cuz Nitti halide Nao
c secondaryamine alkyl tertiaryamine
ethylmethylaminecuz trimethylamine
Foraromaticnaming catsnti cha ctiztctizasctis gy.ggaot'sctisittHzotnaci
Nhs nth tinct's
aniline p chloroaniline salt
in
ntictis chzitctizctiztchzdychs itctizctiz.ci Rynt
common mmethynmethylaniline His
cts Iupac N methyl s methylbenzenamine Foraromatic can be alkylated
Forcycloamine amino cyclotalkan a aniline alkylhalide secondary tertiary
m then s i oh
case case
v u v
aminocyclohexanedimethylaminocyclohexane cis a aminocyclohexane preparationforaminefromreductionofnitrogencompound
Bpofprimary BPofsecondary BPoftertiary asnitrocompound asnaz.no s amine
yo it
HighestBoilingpoint lowestboilingpoint t Nt's
n
amide carboxylicacid alcohol aldehyde amine ether anane isnciz.no
anaon.no
Itis its
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