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Summary IGCSE CAIE CHEMISTRY UNIT 4: ELECTROCHEMISTRY NOTES $2.99   Add to cart

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Summary IGCSE CAIE CHEMISTRY UNIT 4: ELECTROCHEMISTRY NOTES

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IGCSE CAIE CHEMISTRY UNIT 4: ELECTROCHEMISTRY NOTES COMPREHENSIVE NOTES ON UNIT 4: ELECTROCHEMISTRY

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  • July 12, 2024
  • 11
  • 2023/2024
  • Summary
  • Secondary school
  • 4
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Unit 4 Electrolysis
4.1 Electrolysis concepts
Electrolysis is the decomposition of an ionic compound, when molten or in aqueous
solution, by the passage of an electric current.

Only ionic compounds in an aqueous or molten state can undergo electrolysis (the same
goes for metallic compounds but not for covalent compounds)

Key ingredients for electrolysis:

An electrode is a rod of metal or graphite through which an electric current flows
into or out of an electrolyte

Electrolyte the ionic compound in a molten or dissolved solution, containing anions
and cations, that conducts the electricity

An Anode is the positive electrode of an electrolysis cell

A cathode is the negative electrode of an electrolysis cell




Unit 4 Electrolysis 1

, The power supply provides the cathode with a supply of electrons, causing it to become
negatively charged

Positive ions (cations) in the electrolyte move towards the cathode where they gain
electrons

Negative ions (anions) in the electrolyte move towards the anode where they lose
electrons

The electrons move from the anode back towards the power supply

So, in a complete circuit:

Electrons are the charge carriers in the external circuit

Ions are the charge carriers in the electrolyte


Electrolysis of molten compounds and aqueous compounds
w/ examples
Molten compounds
The positive ion will migrate towards the cathode and the negative ion will migrate
towards the anode

Therefore, the cathode product will always be the metal, and the product formed at
the anode will always be the non-metal



Electrolysis of molten lead(II) bromide



Unit 4 Electrolysis 2

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