Summary
Summary Physical properties of organic compounds
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Explanation of physical properties
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PHYSIIALPROPERTIESOFORGANICCOMPOUNDSAlkylHALIDE Chad CHBu Causa Gases
Highermembers are liquids or
solids
B P and M P
FACTORS
Intermolecular
Polarity forces Bianching
Dipole Dipolemovement
VandenWaalforces
comparable masses
BPof chlorides bromides iodides are higherthantheir
CHBr 436 CH F B P
increasing
EH I no of e Tes
Dueto stronginteraction VandenWaalforce attraction
in branched
compound
decreases
of
due to decrease in surfacearea
BPd 1
Branching
so Bpalsodeiveases
Br
Br Br
The mp of monohalogen derivatives ofbenzene F
I Br Ce
0 7 0 s o o o
u U a
a
O O O
U
Generally
ipaazorthoorm
para symmetrical Intermolecularforces higher
Highly
energyrequireto
Greater breakthecomp
DENSITY d
IT
Iodide Bromide chloride fluoride
n GH a n ish f
n GH I n fate Br
halide densityt
If size t in samealkyl Because Mt
CH ChainzI
CH I C CHCH I C mass
Tes s densityt
If atomic massof halogen
Cda CHI 14292 CHI
dissolveslike
Normallypolarcompounds can
be dissolved in HOH like
SOLUBILITY water
low solubility in
but haloalkane have very ether alcohol
solvents like benzene
Can easily dissolve in organic
halide lessenergyreleased
low interactions btw waterandalkyl another reason non bonding
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