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Organic analysis

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These are my notes on organic analysis, including test tube reactions for aldehyde, ketone, alcohol, carboxylic acid and alkenes. This also includes mass spectrometry and infrared spectroscopy.

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  • May 3, 2024
  • 3
  • 2023/2024
  • Class notes
  • Samuel newmarch
  • All classes
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Mass Spectrometry
When passed though a it detects both the whole malute and
again malates specimeter
-


are mass ,




gragments of the maleute .




Molutel passed tagh mass spectants are
gist raised by electing icisation elector import
-
a or




Electospay
imisation : (((g) + H"
<
<High Elector impact : <Cign > <Ciss + e -




-


High resolution muss
sectly
-
ran be used to detinie the moleuter
gamla of the compand from the
accate mass of the older in


If arampard contains banine chance the there will be two molutar in peaks due to the
naturally
-
or
, ,

35(1(75%) and 37 Cl (25% .
veining isotopes
. )




The ratio will be
*
- ChyBe will have M1z values of M of 84 CHE""Br and M +2 of 86 CH3 Br
.

M : M + 2 which is 1 : 1.



Mop8(Hy"C
*
-

Fr C2H + Cln , there will be m1z values of C1
I
M+2 of 100 Camp***C,
and M + 4 of 102 C2Hy ** C * C1 We .
ear calculate the ention of the heights.
3591352 = 75x0 75 = 5625 : 0 375 :
(0
0 .
.
0 .
5625 .
.
0 0625
.




37935(1 1875
3
= 0 75x0 25 : 0
0 375
. . .
= .



35247 = 0 75x0 25 = 0 1875 . .
.
&: 6 :
37913( = 0 25x0 25 = 0 0625
. .
.




CuHy35(35(
*

C2HyCla will have miz values of M
of 132 C1 M+2 of 134 (4**(15(15C ,
-



,

CHzc* /
**
M + 4 of 136 (2Hy37(137(135C end M+ 6 of 138 C



35(1354354 : 0 75x0 75x0 75 = 0 4218
. . . .
.4219 : 0 4218 : 0 1406 : 0 0156
0 . . .



35(377354 = 0 75x0 2540 75x3 = 0 4219
. . . .
i
0 0156
35(13793721 = 0 7540 25x0 25x3 = 0 1406 -27 : 27 : & : /
.


.
. . .




37(127(137( = 0 . 25 x 0 25x0 25 : 0
.
.
. 0156

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