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Pearson Edexcel Summer June 2023 Pearson Edexcel GCE In Chemistry (8CH0) Paper 02 Core Organic and Physical Chemistry $16.49   Add to cart

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Pearson Edexcel Summer June 2023 Pearson Edexcel GCE In Chemistry (8CH0) Paper 02 Core Organic and Physical Chemistry

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Pearson Edexcel Summer June 2023 Pearson Edexcel GCE In Chemistry (8CH0) Paper 02 Core Organic and Physical Chemistry

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  • November 30, 2023
  • 34
  • 2023/2024
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Please check the examination details below before entering your candidate information

Candidate surname Other names


Centre Candidate
Number Number


Pearson Edexcel Level 3
GCE
Tuesday 23 May 2023

8CH0/02
Paper
Morning (Time: 1 hour 30
reference
minutes)

Chemistr
 


Advanced Subsidiary
y
PAPER 2: Core Organic and Physical
Chemistry
You must have: Total
Scientific calculator, Data Booklet, ruler Marks



Instructions
• Use
• IfFillpencil
black ink or ball‑point pen.
is used for diagrams/sketches/graphs it must be dark (HB or B).
• in the boxes at the top of this page with your name,
centre number and candidate number.
• Answer all
• Answer
provided
the questions in the spaces
questions.– there may be more space than
you need.

Information
• The
• – usemarks
total mark for this paper is 80.
The for each question are shown in brackets

• For the question marked with an asterisk (*), marks will be awarded for your
this as a guide as to how much time to spend on each question.

ability to structure your answer logically, showing the points that you make

• are related or follow on from each other where appropriate.
A Periodic Table is printed on the back cover of this paper.

Advice
• Read

each question carefully before you start to answer it.
Show all your working in calculations and include units where appropriate.

• Check your answers if you have time at the
Turn over
end.

final

, Answer ALL questions.

Some questions must be answered with a cross in a box . If you
change your mind about an answer, put a line through the box and
then mark your new answer with a cross .

1 This question is about collision theory.

The Maxwell‑Boltzmann distribution of molecular energies for a reaction at a
particular temperature is shown in the graph.

Add another line on the graph to represent the same reaction with the same
number of particles at a higher temperature.




Number of
particles with
energy, E




Energy, E


(Total for Question 1 = 2 marks)




2


,2 This question is about alkanes and some of their reactions.

(a) Hexane is a saturated hydrocarbon.

State what is meant by the term ‘saturated hydrocarbon’.
Your answer should refer to both words in the term.
(2)

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......................




(b) When methane reacts with gaseous chlorine, the initiation step is bond
breaking in the chlorine molecule to form chlorine free radicals.

The equation for this step is shown.

Cl2(g) → 2Cl•(g)

Two equations for the propagation step are shown.

Cl•(g) + CH4(g) → CH3•(g) + HCl(g)
CH3•(g) + Cl2(g) → CH3Cl(g) +
Cl•(g)

(i) Write the overall equation for this reaction of methane with
chlorine. State symbols are not required.
(1)




(ii) Calculate the maximum mass, in grams, of chloromethane produced
when
7.00 g of chlorine gas reacts completely with excess

methane. [Molar mass of CH3Cl = 50.5 g mol–1] (2)




3
 Turn over

, (iii) Write an equation for a termination step for this
reaction. State symbols are not required.
(1)




(iv) Further substitution of chloromethane can occur, producing
dichloromethane, which is a liquid at room temperature.

Calculate the maximum volume, in cm3, of dichloromethane liquid that
could be produced from 12.5 g of chloromethane.
Give your answer to an appropriate number of significant figures.
(3)

CH3Cl(g) + Cl2(g) → CH2Cl2(l) + HCl(g)

[Density of dichloromethane, CH2Cl2(l) = 1.32 g cm–3]




4


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