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Summary of necessary background information Nanomaterials: chemistry and fabrication (6E12X0) $5.41   Add to cart

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Summary of necessary background information Nanomaterials: chemistry and fabrication (6E12X0)

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This document describes the prior knowledge assumed all students have before the start of the course Nanomaterials: chemistry and fabrication.

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  • May 15, 2023
  • 2
  • 2022/2023
  • Class notes
  • Catarina carvalho esteves
  • Lecture 1
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IBMGRN ERCQCCLOESSF
NENDORSES T
nanotechnologytechnology?
basics of




nanotechnology: atomic, molecular or macro-molecular level in a
length scale 1-100
of nanometers


more of these small "clumps"can be added to grow above this range


the size of nanotechnology should be the cause for new properties / functions


you should be able to control/manipulate on the nanometer/subnanometer/atomic scale


Richard Feynman:the father nanotechnology
of


he wasn't
recognized his
at time but later on received the nobel prize


he thought he could store more computer information on a smaller computer


ne used synthesis chemistry to make particles smaller causing them to behave differently

making nanomaterials


top-down:starts bulk
at (micro-or milli-scale) and is crushed to become smaller (nanometer)

bottom-up manipulating atoms to create larger objects in the nanometer scale


most used by chemists


atomic basics

atoms:fundamental building blocks matter
of



element:identifies the type of atoms


defined by the number o fatoms


molecules:a set of at least 2 atoms in different
arrangements held together by chemical forces

compound:composed different
of types of atoms


ion:(groups of atoms with net positive/negative charge

quantum numbers:

principal quantum number (n):defines size & energy levels


indicates the shell where the electron is

a greater means a large orbital and more energy

atomic weight determines where the electrons will be


angular quantum number (1):determines subshell where electron is for
a given n



possible integral values between 0 and n- |



the orbital has a unique shape and letter


shape gives information on the angular node at an orbital


angular node:region where there will likely benoelectrons


magnetic quantum number (mi):defines the orientation


for a given (there's 21+1 integral values

spin quantum number (ms) determines spinning motions of electrons


MS "/2
=

or MS = -
1/2

chemical bonds

electronegativity:measures the ability of an atom to attract an electron


polarity:more charge on one side then the other


bonding electron
covalent sharing between non-metallic atoms


can create molecules or networks of solids


types of bonds:


sigmabond (0):the overlap of as particles

creates single b onds
covalent


atoms can rotate freely like beads on a string

pibond (TT):overlap a
of parallel p-orbitals

forms I areas of electron densities above and below the molecule formed

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