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Preparation of phenol and it's properties

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phenol all course available. it is preparation of phenol and chemical properties and physical properties.

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  • September 10, 2022
  • 25
  • 2022/2023
  • Interview
  • Unknown
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  • Secondary school
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Phenol
Hydroxy derivative of aromatic hydrocarbon in which –OH
group is directly bonded to aromatic ring is called Phenol.
OH


Preparation of phenol :
1. From chlorobenzene (Dow’s process):
Chlorobenzene when heated with sodium hydroxide at 350°C
and 300 atm pressure gives sodium phenoxide which on
acidification with dil. HCl, yield phenol .
Cl ONa

350°C
+ NaOH + HCl
300 atm

, ONa OH

+ HCl + NaCl


2. From diazonium salt:
On warming aq. solution of benzene diazonium salt in the
presence of little dilute sulphuric acid, phenol is obtained .
N=N-Cl
OH
H2O/H +

+ N2 +HCl

3. From sulphonic acid :
Sodium salt of benzene sulphonic acids on fused with sodium
hydroxide (solid) at 300°C followed by acidification gives
phenol.

, SO3Na ONa

2NaOH
+ Na2SO3 + H2O
Fuse
ONa OH

+ HCl + NaCl



4. By decarboxylation of sodium salicylate:
Sodium salicylate on distillation with sodalime
followed by acidification , phenol is obtained .

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